Kevin De Bruyne's perfectly-struck goal shorly after the break and a late Raheem Sterling effort gave Manchester City a 2-0 win over Shakhtar Donetsk.
Pep Guardiola's side have now won their opening two Champions League games following an opening-night victory over Feyenoord.
But City's Argentine striker Sergio Aguero missed a chance to equal the club's all-time scoring record when his penalty midway through the second half was saved.
The miss left him one goal behind Eric Brook's record of 177 goals in all competitions - but Sterling did strike at the death.
The Premier League leaders now top Group F on six points with Shakhtar and Napoli both on three points.
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